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Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks

Vincent Marichez, Akihiro Sato, Peter A. Dunne, Jorge Leira-Iglesias, Georges J. M. Formon, Michaela K. Schicho, Isja de Feijter, Pascal H├ębraud, Matthieu Bailleul, Pol Besenius, Munuswamy Venkatesan, J. M. D. Coey, E. W. Meijer, and Thomas M. Hermans

Published: 11 August 2021

Abstract

Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.

Full Access Link: Journal of the American Chemical Society